effect of impregnation method on carbon supported catalyst activity

The effect of catalyst preparation method on the …

The concentration of the solution of the mixed aqueous solution of HAuCl 4 and PdCl 2 immediately prior to the initial drying step has a profound effect on the structure and activity of the TiO 2-supported catalysts. TiO 2-supported catalysts prepared using impregnation with the minimal amount of added water whilst ensuring that the catalyst is ...

Catalysts | Free Full-Text | Effect of Preparation Methods …

2021-6-7 · A series of Pt/TiO2 catalysts were prepared by the impregnation (IM), dry ball mill (DB), or wet ball mill (WB) methods, and their catalytic activity for the oxidation of CO was evaluated. The structure and redox properties of the catalysts were investigated by N2 desorption, XRD, SEM, TEM, XPS, H2-TPR, SO2-TPD, and CO chemisorption analysis. It was …

Effect of preparation method on the activity of bimetallic …

2021-2-2 · These changes have a favorable effect on the activity of the Ni-Co/γ-Al 2 O 3 (SC) catalyst in the process under study. At a low reaction temperature (600 °C) on the sample by the synthesized solution combustion method, the methane conversion is higher (X CH4-69%) compared to the method of capillary impregnation of the support (X CH4-65%).

Recent Developments in the Synthesis of Supported …

2015-6-19 · This can have a negative effect on the resulting catalyst, such as with the impregnation of aqueous cobalt nitrate on γ-alumina. ... Two main impregnation methods are distinguished, namely, wet impregnation (WI), whereby an excess amount of solution is used, and pore volume impregnation (PVI), in which an amount to just fill the pore volume of ...

Development of Mo-Modified Pseudoboehmite Supported …

2022-7-29 · In addition, the effects of various catalysts on the carbon-containing product selectivity are shown in Figure 10b. The CH 4 selectivity gradually increases with an increase in Ni/Mo ratio, and the CH 4 selectivity reaches a minimum of 0.095% for the Ni1Mo1/PB catalyst; the CH 4 selectivity of the Ni10Mo1/PB catalyst reaches a maximum of 0.83%.

Effect of N, P co-doped activated carbon supported Cu …

2022-4-1 · For investigating the effects of doped support and loaded active components on catalyst structures, we study the structural parameters of fresh AC, 20NPAC and Cu/xNPAC catalysts by N 2 adsorption desorption method. The result in Fig. 2a shows that the adsorption capacity of all catalysts increases sharply at the relative pressure P/P 0 of 0.001, and shows …

EXAFS Peaks and TPR Characterizing Bimetallic …

For TPR study, Pt/C and Ru/C catalysts were prepared by impregnation of carbon black with H 2 PtCl 6 and RuCl 3, respectively, followed by drying at 80°C. Pt-Pd/γ-Al 2 O 3 catalyst was prepared by successive impregnation method using H 2 PtCl 6 and Pd(O 2 CCH 3) 2 as Pt and Pd precursors, respectively, and was denoted as Pt-Pd(OAc) 2 /γ-Al 2 ...

The comparative jurisprudence of catalysts preparation …

2018-3-5 · Factors affect the impregnation method. There are some factors affect the as prepared catalysts by impregnation method such as temperature and the concentration of precursor. The operating variable is the temperature, which influences both the precursor solubility and the solution viscosity and as a consequence the wetting time.

Effect of impregnation methods on nickel-tungsten …

Three hydrocracking catalysts were prepared by impregnation method with different incorporation manners of Ni/W metals on HY/Al 2 O 3 support. The effect of combination methods on acidity, hydrogenation capability of the catalysts and its hydrocracking performance on FT wax was studied. The balance between hydrogenation performance and cracking performance could be …

Effects of preparation methods on the properties of …

2014-7-25 · The effect of different impregnation methods on the catalyst activity was shown in Fig. 1. It revealed that the activity of catalyst prepared through incipient-wetness impregnation method was higher than that of catalyst prepared through excessive impregnation method, viewed from the conversion of reaction feed gas and selectivity of synthesis gas.

The effect of impregnation sequence on the …

2008-3-2 · The effect of impregnation sequence on the formation of Pt/Ni bimetallic nanoparticles supported on g-Al 2 O 3 was investigated for catalysts with Pt/Ni atomic ratios of 3/1 and 1/1.

Effect of preparation method on the structure and catalytic …

2010-12-1 · In the present study, we prepared a series of supported nickel catalysts with two different preparation procedures using NaBH 4 and N 2 H 4 ·H 2 O as reducing agents. The effects of different preparation methods on catalyst structure and catalytic activity were investigated, and a relationship of the structure and performance was proposed. 2 ...

The Effect of Preparation Method of Ni-Supported SiO2 …

2021-10-10 · Reforming methane to produce syngas is a subject that generates considerable interest. The process requires catalysts that possess high-performance active sites to activate stable C–H bonds. Herein, we report a facile synthetic strategy to prepare Ni-based catalysts by complexation–impregnation (Ni-G/SiO2-C) and precipitation–impregnation (Ni-G/SiO2-P) …

(PDF) Effects of preparation variables on an alumina …

All of the supported catalysts were 45 alyst was higher (6–7 mol%, carbon atom basis). also calcined in dry air after each metal impregnation step for O''Brien et al.2 used a different impregnation method for 16 h at 300 °C. preparing supported …

Effect of different catalyst preparation methods …

2018-3-13 · The peak area of the catalyst prepared by the impregnation method is 22% less than that of the sol-gel method, it shows that the content of iron catalyst particles is less, the iron particles are not easy to reunite, and the …

Factors Influencing Hydrogenation and Decomposition of …

The bimetallic Pd–Au catalysts were prepared by simultaneous co-impregnation or consequent impregnation of supports by palladium and gold precursors. The catalytic reactions were performed batch-wise in a Parr stainless steel autoclave and methanol (220 ml) was used as solvent. A series of experiments were conducted to study effects of several variables and …

(PDF) Copper supported on porous activated …

An activated carbon-supported copper heterogeneous catalyst based on (Cu/AC) was developed using a wetness impregnation process. The effect of preparation conditions on the catalyst''s ...

Effect of Preparation Method on the Catalytic Activities of …

2015-4-28 · Abstract Pd–Cu/APT catalysts were prepared by an impregnation method (PC-IM) and an evaporation ammonia method (PC-AE), respectively. Their catalytic activities for low-temperature CO oxidation were studied. It is found that PC-AE shows much higher catalytic activity. Characterizations results suggest that Cu species exist as the Cu2(OH)3Cl phase with …

Effect of Order of Impregnation of Mo and Ni on the ...

The influence of order of the impregnation of NiO and MoO3 on the structure and catalytic behavior of H-AlMCM-41 supported Ni−Mo catalysts for hydrodenitrogenation (HDN) has been investigated. These catalysts were well characterized by TEM, XRD, N2 adsorption−desorption, XPS, and FT-IR spectra of CO adsorption and tested for hydrodenitrogenation (HDN) of o …

SciELO

It was reported that impregnation method significantly affected the structure, dispersion, and chemical states of Ni and Mo species on the sulfided Ni-Mo catalysts, hence affected the HDN activity for Ni-Mo based catalysts. 14,15 It was also reported that sulfided Ni-W catalysts are superior to sulfided Ni-Mo catalysts for HDN because of their ...

Effects of Preparation Method on the Characterization and …

2021-7-1 · Carbon monoxide oxidation, which is important for many applications, was studied on Vulcan XC72 supported CuO–CeO2 catalysts. The effects of surfactant and solvent used in impregnation technique on the characterization and activities of the catalysts were investigated. During the impregnation process, water, 1-propanol, ethyl alcohol, acetone and ethylene glycol …

Studies on the catalyst preparation methods and kinetic …

2015-1-1 · Low cost dispersed supported cobalt oxide nanocatalysts on activated carbon (AC) were prepared by two different methods: (1) combined impregnation and deposition–precipitation (IMP-DP) and (2) heterogeneous deposition–precipitation (HDP). XRD, TEM, FESEM, BET and Boehm techniques were used for the characterization of the support and the catalysts. …

Synthesis of highly dispersed Pt nanoparticles into carbon …

2020-6-12 · To demonstrate the Pt catalyst activity by FBR-ALD, the CV curves of Pt/Vinatech, Pt/Vulcan and commercial Pt/carbon catalyst in 0.1 M HClO 4 with a 20 mV/s sweep are illustrated in Fig. 6a.

Intrinsic Effect of Carbon Supports on the Activity and …

2020-5-25 · Author Manuscript Title: Intrinsic effect of carbon supports on the activity and stability of precious metal group (PMG)-based catalysts for electrocatalytic alcohol oxidation of fuel cells Authors: San Ping Jiang, Dr.; Jin Zhang; Shanfu Lu; Yan Xiang This is the author manuscript accepted for publication and has undergone full peer

Effect of different catalyst preparation methods on the …

2018-3-13 · The peak area of the catalyst prepared by the impregnation method is 22% less than that of the sol-gel method, it shows that the content of iron catalyst particles is less, the iron particles are not easy to reunite, and the diameter of the carbon nanotubes synthesized by the catalysts prepared by the impregnation method is also greatly reduced.

Effect of impregnation strategy on catalytic hydrogenation ...

1 Fengjun Hou;Huahua Zhao;Huanling Song;Lingjun Chou;Jun Zhao;Jian Yang;Liang Yan;;Effect of impregnation strategy on catalytic hydrogenation behavior of PtCo catalysts supported on La_2O_2CO_3 nanorods[J];Journal of Rare Earths;201809 2 Guang-Yin ...

Catalytic Oxidation of Propene over Pd Catalysts …

In the following work, the catalytic behavior of Pd catalysts prepared using different oxides as support (Al2O3, CeO2 and TiO2) in the catalytic combustion of propene, in low concentration in excess of oxygen, to mimic the conditions of catalytic decomposition of a volatile organic compound of hydrocarbon-type is reported. In addition, the influence of different promoters …

Effects of impregnation methods and drying conditions on …

The effects of impregnation methods (co-impregnation and sequential impregnation) and drying conditions (air and vacuum) on the structure and catalytic behavior of MCM-41 supported Ni-W catalysts were investigated. The catalysts were characterized by powder X-ray diffraction (XRD) analysis, Fourier-transform infrared spectroscopy (FT-IR ...

Activity of Carbon-Supported Catalysts

The wealth of information on the activity of carbon-supported catalysts obtained at a near atmospheric pressure of H2 has been noted. It may appear that the value of such results is somehow limited. However, in most cases, the activity was determined in parallel with characterization of active phase by spectroscopic techniques and other methods.

Effects of metal impregnation on ZSM-5 for catalytic …

2020-9-23 · Metal impregnation has been studied as a method to develop improved catalysts for use in catalytic upgrading of biofuel intermediates. To investigate the effectiveness of metal impregnation, metal-modified catalysts were prepared via incipient wetness impregnation using Ni, Cu, Pt, Co, and Ga precursors on the zeolite ZSM-5. The

Preparation of activated carbon-supported Co-Mo …

2012-2-24 · Supported Co-Mo catalyst was prepared by impregnation-precipitation method using modified activated carbon as carrier and urea as precipitant.Catalytic activity of catalyst was studied by using the reduction of SO 2 by CO.Under optimum reaction conditions (sulfidation temperature 500℃; GHSV=7 000 mL·g-1 ·h-1;CO/SO 2 mol ratio =2:1; reaction temperature …

Impregnation method prepared Cu-Co-Ce-O catalysts and …

2012-9-6 · The results showed that the Co/Ce atomic ratio has great effect on the activities of catalysts, and the catalyst with Co/Ce = 1 has the highest catalytic activity for …

Effect of impregnation solvent on Ni dispersion and …

2016-2-1 · In order to take a deep insight into the effect of impregnation solvent, the activities of the catalysts were repeated at a higher WHSV of 30,000 ml/g/h, and the results were shown in Fig. 6E and F. The CO conversion and CH 4 yield deceased with the increasing of the space velocity. Compared the activity of the catalysts prepared by different ...

Effect of Preparation Methods on the Performance of …

2016-8-16 · Abstract A series of Pt/CeO2 catalysts were prepared by impregnation (IM), deposition-precipitation (DP) and impregnation-reduction (IR) methods, and their catalytic activities for the oxidation of CO were evaluated at room temperature. Pt/CeO2 (IR) catalyst presented the best catalytic activity, over which CO could be completely oxidized at room …

The role and effect of CdS-based TiO2 photocatalysts …

2022-7-30 · The 0.1% CdS-based TiO 2 photocatalysts with different atomic ratios were synthesized by the wetness impregnation (WI) method. These photocatalysts were characterized to actively determine surface area using TPx analyses (TPR, TPO, and TPD).Furthermore, surface structures and properties of photocatalysts were defined by analyses such as XRD, …

Impact of the Experimental Parameters on Catalytic …

2022-3-30 · Sol immobilization is used to produce bimetallic catalysts with higher activity to monometallic counterparts for a wide range of environmental and commercial catalytic transformations. Analysis of complementary surface characterization (XPS, Boehm''s titration, and zeta potential measurements) was used to elucidate alterations in the surface functionality of …

(PDF) Effect of phosphorus on activity of hydrotreating …

The HDS of heavy crude preferably depends on However, catalysts prepared by two-step impregnation method, the active sites whereas for the HDM reaction, the pore either P impregnated first or latter, have less polymolybdate structure of the catalyst is an important factor to be considered. species, but these molybdate species reduce at lower ...

Ionomer distribution control in porous carbon-supported …

2019-9-30 · Mass activities of all catalysts were found to be around 350 mA per g of Pt (g Pt) at 0.9 V, thus confirming no influence of carbon support modification on …

Effect of Rhenium on the Catalytic Activity of Activated …

2022-3-18 · This work evaluates the performance of activated carbon-supported Ni and Re catalysts in the hydrogenation of furfural and levulinic acid. The increase in Re content enhances Ni dispersion, decreases Ni reducibility and increases acidity. The Lewis acidity on the catalysts was attributed to unreduced Ni and Re species, while the Bronsted acidity, to Re–OH species …

The comparative jurisprudence of catalysts preparation …

2022-5-2 · It is one of the most widely employed catalysts preparation methods and may be used to prepare either single component catalysts or supported and mixed catalysts [3- 9]. In other words, this method can be used to prepare bulk and supported catalysts. This process is centered on the combination of aqueous phase